WEBFeb 15, 2024 · Based on the multistage liquefaction process, asphaltene was prepared from Hongliulin coal and deeply liquefied with NiCoMo, CoMo, and Fe2 O 3 alysts. The yields of each component were obtained. Ultimate analysis, FTIR and XPS was used to investigate the conversion of oxygenic structure. The results showed that the ability to .
WhatsApp: +86 18203695377WEBOct 1, 1984 · Process slurries emanating from reactors generally contain 5 to 10 wt.% of solids. Solid—liquid separation processes must be used to separate the mineral residue and unconverted carbon from liquefied coal. Difficulties in removing those solid components represent a major obstacle to economic production of liquefied coal products.
WhatsApp: +86 18203695377WEBHydrothermal liquefaction (HTL) is a thermal depolymerization process used to convert wet biomass, and other macromolecules, into crudelike oil under moderate temperature and high pressure. The crudelike oil has high energy density with a lower heating value of MJ/kg and 520 wt% oxygen and renewable chemicals. The process has also .
WhatsApp: +86 18203695377WEBJun 1, 2017 · 1. Overview of DCL process and the behaviors of mineral matter in liquefaction. Direct coal liquefaction, which is known as DCL, refers to the process that involves direct hydrogenation of coals at relatively high temperatures and pressures [1], [2].It can be also viewed as a reductive pyrolysis process in which raw .
WhatsApp: +86 18203695377WEBJan 1, 1983 · Curran et al. (1966, 1967) were the first to describe the general mechanism of coal liquefaction as a free radical process in which coal is thermally decomposed into free radicals subsequently stabilized by abstraction of hydrogen: Free radicals are now believed to play a major role in liquefaction processes (see Neavel, 1976b). Coal has ...
WhatsApp: +86 18203695377WEBMar 13, 2024 · The direct coal liquefaction (DCL) process converts coal directly into liquid fuel under high temperature and pressure in the presence of a hydrogendonating solvent. DCL is one such technology which falls in clean coal conversion technologies. The solvents also play an important role in the DCL process.
WhatsApp: +86 18203695377WEBNov 21, 2000 · Direct coal liquefaction test plants have been constructed and successfully operated under subsidies from the New Energy and Industrial Technology Development Organization. To analyze the data, which had been collected on these plants, a simulator was constructed for the material and enthalpy balances in the preheaters and reactors. .
WhatsApp: +86 18203695377WEBOct 1, 1982 · The basic process, which can be considered 'second generation' relative to other coal liquefaction processes under development today, is called the Chevron Coal Liquefaction Process (CCLP). This process and its variants have been studied in integrated laboratoryscale pilot plants with capacities of — kg (coal) day −1.
WhatsApp: +86 18203695377WEBHydrogen transfer cycle for coal liquefaction process impliions. Conference · Fri Jan 01 00:00:00 EST 1988 · Prepr. Pap., Am. Chem. Soc., Div. Fuel Chem.; (United States) Direct liquefaction of coal involves the conversion of a hydrogenpoor solid to a liquid richer in hydrogen by a complex set of bond ruptures and a hydrogen transfer ...
WhatsApp: +86 18203695377WEBMay 1, 2000 · A coal liquefaction pilot plant of the NEDOL process, supported by the New Energy and Industrial Technology Development Organization (NEDO), was in successful operation for a total of 269 days at Kashima, Japan. The liquefaction section consisted of three reactors, 1 m in diameter, connected in series, and processed 150 tons of coal .
WhatsApp: +86 18203695377WEBFeb 1, 2000 · Coal liquefaction residue (CLR) is a byproduct from direct coal liquefaction process, usually accounting for 30 wt.% of the feed coal [7, 8]. CLR is considered as a potential carbon resource for ...
WhatsApp: +86 18203695377WEBHighlights. Coal liquefaction, the conversion of coal to a cleanburning, lowsulfurcontent fuel, is a technology that can augment petroleumderived products such as gasoline and boiler fuels and help meet the requirement for large supplies of liquid fuel. Direct liquefaction produces liquids through the interaction of coal and hydrogen at ...
WhatsApp: +86 18203695377WEBOct 29, 2009 · Description: The Solvent Refined Coal liquefaction process referred to as SRCII is a thermal liquefaction process; it is an outgrowth of an earlier Solvent Refined Coal process tested by Gulf Oil in the 1960s [20,21,22,23,24]. The earlier process, known as SRCI, was aimed at boiler fuel production of an ashless lowsulfur solid fuel.
WhatsApp: +86 18203695377WEBDirect coal liquefaction residue (DCLR) is, commonly, designed to be used as a feed stock for gasifiion or combustion. Use of DCLR as a value added product is very important for improving overall economy of direct coal liquefaction processes. This study shows that the DCLR may be used as a pavement asphalt modifier. The modifiion ability is similar to .
WhatsApp: +86 18203695377WEBMar 27, 2023 · Background Indirect coal liquefaction differs fundamentally from direct coal liquefaction in that the coal is first converted to a synthesis gas (a mixture of H2 and CO) which is then converted over a alyst to the final product. Figure 279 presents a simplified process flow diagram for a typical indirect coal liquefaction process.
WhatsApp: +86 18203695377WEBFeb 1, 2000 · A maximum oil yield in the NEDOL coal liquefaction process was obtained with coal containing 76−78% carbon, while gas and water yields decreased with an increase in the carbon content. On the other . Expand. 3. Save. Additive Effect of Waste Tire on the Hydrogenolysis Reaction of Coal Liquefaction Residue.
WhatsApp: +86 18203695377WEBA process for liquefying a particulate coal feed to produce useful petroleumlike liquid products by steps which include: (a) contacting, in a liquefaction zone, said coal feed with a hydrogen donor solvent at temperature and pressure sufficient to hydroconvert and liquefy the coal, (b) separating the product from the liquefaction zone by distillation into .
WhatsApp: +86 18203695377WEBA general quantitative validation of the new kinetic model for SRCII coal liquefaction (Singh et al., 1981 a) is obtained by very good agreement between model predicted and measured yields. This shows that the new kinetic model provides a reasonable representation of the overall intrinsic process of SRCII coal liquefaction and hence, it .
WhatsApp: +86 18203695377WEBJan 19, 2023 · Liquefaction. Coal liquefaction is a process of converting coal into liquid fuels or petrochemicals. There are several processes to accomplish this task. The two most common are the indirect route and the direct route [58, 59].
WhatsApp: +86 18203695377WEBJan 27, 2010 · The growing demand for petroleum, accompanied by the declining petroleum reserves and the concerns over energy security, has intensified the interest in direct coal liquefaction (DCL), particularly in countries such as China which is rich in coal resources, but short of petroleum. In addition to a general introduction on the mechanisms and .
WhatsApp: +86 18203695377WEBMar 1, 1993 · The work described is primarily concerned with the appliion of coal cleaning methods and solids separation methods to the Catalytic TwoStage Liquefaction (CTSL) Process. Additionally a predispersed alyst was evaluated in a thermal/alytic configuration, and an alternative nickel molybdenum alyst was evaluated for the .
WhatsApp: +86 18203695377WEBSep 1, 2011 · Highlights A novel liquefaction and distillation process is designed for oxygen bearing coalbed methane. Oxygen contained in coalbed methane is removed in distillation process. Flammability limits are analyzed for the whole operation process. We find explosion hazard may exist in distillation tower. Effective measures are proposed to .
WhatsApp: +86 18203695377WEBCoal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur). ...
WhatsApp: +86 18203695377WEBDec 1, 2022 · Nowadays, to reduce the cost of coal liquefaction and to produce a new liquid fuel alternative to petroleum, it is considered a more convenient method to liquefy coal and biomass together instead of solely coal liquefaction. ... Depending on the liquefaction process conditions, the carbon, hydrogen, sulfur, nitrogen, and oxygen .
WhatsApp: +86 18203695377WEBFeb 15, 2024 · Based on the multistage liquefaction process, asphaltene was prepared from Hongliulin coal and deeply liquefied with NiCoMo, CoMo, and Fe 2 O 3 alysts. The yields of each component were obtained. Ultimate analysis, FTIR and XPS was used to investigate the conversion of oxygenic structure. The results showed that the ability to .
WhatsApp: +86 18203695377WEBAbstract. Interest in direct coal liquefaction steadily decreased during the 1980s as the price of crude oil dropped; there is now only one integrated coal liquefaction pilot plant active full time in the United States. The economics derived early in the decade established the price of transportation fuels from coal at 80 per barrel or higher.
WhatsApp: +86 18203695377WEBOn the surface, it looks pretty much the same as the process of coal liquefaction. It is a thermochemical conversion process of organic material into liquid biocrude and coproducts. Depending on the process, it is usually conducted under moderate temperatures (300400°C, lower than coal liquefaction) and pressures (1020 MPa, similar or ...
WhatsApp: +86 18203695377WEBJan 1, 2015 · Recently, a new direct coal liquefaction process that uses no alyst was shown to operate at temperatures below 360 °C [6 ... In coal liquefaction, the major chemical reactions in the presence of hydrogen are hydrogenolysis of C–C, C–O, C–N, and C–S bonds, and hydrogenation of aromatic rings; these reactions convert coal to smaller ...
WhatsApp: +86 18203695377WEBJan 1, 2008 · Coal rank and composition are primary factors that influence liquefaction behavior (Fisher et al., 1942) and, although some of that influence may be overcome by increasing process severity or the use of alysts, these options may be counterproductive in reducing operating expenses (Alpert and Wolk, 1981).
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